Pentafluorophenylplatinum Complexes containing η1- or η2-Aryl-Pt Interactions. Crystal Structure of cis-2-Ph)Ph>-2>-κN)>*0.5C6H5Me

DOI: 10.1039/DT9950002949

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2949 - 2954 (1995)

Update date:2022-07-30

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Authors:

Casas, Jose M.

Fornies, Juan

Martin, Antonio

Menjon, Babil

Tomas, Milagros

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Article abstract of DOI:10.1039/DT9950002949

The reaction of cis-> 2 and cis-> 3 respectively.The solid-state structure of 2 has been established by X-ray diffraction methods and reveals the existence of a η²-phenyl-Pt interaction which is maintained in solution (NMR).Crystal data for 2*0.5C6H5Me: C33.5H19F10NPt, triclinic, space group P<*>, a = 11.653(4), b = 12.345(3), c = 12.499(4) Angstroem, α = 116.91(2), β = 104.33(2), γ = 103.41(2) deg, Z = 2, R =0.038 for 2791 unique 'observed' absorption-corrected reflections collected at 233 K.Complexes 2 and 3 reacted with CO yielding cis-(CO)> and cis-(CO)> respectively.

Full text of DOI:10.1039/DT9950002949

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