Pentafluorophenylplatinum Complexes containing η1- or η2-Aryl-Pt Interactions. Crystal Structure of cis-2-Ph)Ph>-2>-κN)>*0.5C6H5Me

DOI: 10.1039/DT9950002949

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2949 - 2954 (1995)

Update date:2022-07-30

Topics:

Authors:

Casas, Jose M.

Fornies, Juan

Martin, Antonio

Menjon, Babil

Tomas, Milagros

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950002949

The reaction of cis-> 2 and cis-> 3 respectively.The solid-state structure of 2 has been established by X-ray diffraction methods and reveals the existence of a η²-phenyl-Pt interaction which is maintained in solution (NMR).Crystal data for 2*0.5C6H5Me: C33.5H19F10NPt, triclinic, space group P<*>, a = 11.653(4), b = 12.345(3), c = 12.499(4) Angstroem, α = 116.91(2), β = 104.33(2), γ = 103.41(2) deg, Z = 2, R =0.038 for 2791 unique 'observed' absorption-corrected reflections collected at 233 K.Complexes 2 and 3 reacted with CO yielding cis-(CO)> and cis-(CO)> respectively.

Full text of DOI:10.1039/DT9950002949

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:cis-bis(benzylamine)bis(pentafluorophenyl)platinum(II)

Cas No:171975-61-4

R&D Labs maybe for 171975-61-4

ZCIC INTERNATIONAL LTD

Contact:+86-512-56795332

Address:No227 Shuanglong Rd, Fenghuang, Zhangjiagang
NEWSTAR CHEM ENTERPRISE LTD.

Contact:0572-2722882

Address:1201,F3,xinghuibandao,
ZhangJiaGang YaRui Chemical Co.,Ltd.

Contact:0512-58360968

Address:China JiangSu Province Zhang Jia Gang City YangShe Oriental Plaza Building 10 B307
Shanghai ZaiQi Bio-Tech Co., Ltd.,

Contact:+86-21-5482 4098

Address:Bldg. No.7, No.201 MinYi Rd，Songjiang CaoHeJing High-Tech Park Shanghai 201516 P,R,China
Phytomarker Ltd.(expird)

Contact:+86-22-26358246

Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China

Relevant to this article

Total synthesis of 2'-O-methyl-β-L-arabinosyluridine and reassignment the nucleoside from penicillium sp. as 2'-O-methyl-β-L-uridine

Doi:10.1016/j.phytol.2020.01.018
(2020)
Doi:10.1021/ja01265a049
(1939)
Synthesis of trisphaeridine and norchelerythrine through palladium-catalyzed aryl-aryl coupling reactions

Doi:10.1039/b008683p
(2001)
Thiocyanation and 2-Amino-1,3-thiazole Formation in Water Using Recoverable and Reusable Glycosylated Resorcin[4]arene Cavitands

Doi:10.1021/acs.joc.0c01150
(2020)
An efficient synthesis of an alphavbeta3 antagonist.

Doi:10.1021/jo030297u
(2004)
Doi:10.1016/S0040-4039(01)99936-8
(1966)

Article Doi