First evidence for the formation of a geminal dizinc carbenoid: A highly stereoselective synthesis of 1,2,3-Substituted cyclopropanes

DOI: 10.1021/ja017230d

Source and publish data:

Journal of the American Chemical Society p. 386 - 387 (2002)

Update date:2022-07-29

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Authors:

Charette, Andre B.

Gagnon, Alexandre

Fournier, Jean-Francois

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Article abstract of DOI:10.1021/ja017230d

Significant amounts of novel gem-dizinc carbenoids (RZnCHIZnR) are formed when diethylzinc is mixed with iodoform in CH₂Cl₂ at 0 °C. This reagent was shown to be effective in the cyclopropanation of butenediol derivatives to generate

Full text of DOI:10.1021/ja017230d

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