Russian Chemical Bulletin p. 881 - 886 (1999)
Update date:2022-08-05
Topics:
Pisarenko
The oxidation of tetrachlorohydroquinone in an aqueous solution at pH 7.40 is an autocatalytic reaction (sigmoid kinetic curves). The interaction of the tetrachloro-1,4-semiquinone radical anion with dioxygen occurs with the rate constant k2 equal to 9±3 L mol-1 s-1 (22-37 °C). Superoxide dismutase does not affect the maximum rate of tetrachlorohydroquinone oxidation.
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