Tetrahedron Letters p. 8557 - 8560 (1993)
Update date:2022-08-03
Topics:
Coombes, Robert G.
Diggle, Andrew W.
Kempsel, Stewart P.
The apparent rate of reaction of 2,4,6-trialkylphenols with nitrogen dioxide in solution is that of a 6-nitrocyclohexa-2,4-dien-1-one to 4- nitrocyclohexa-2,5-dien-1-one isomerisation unless the 2- and 6-alkyl groups are sufficiently bulky when the rate limiting stage may involve reaction between the appropriate phenoxy radical and NO2.
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