Synthesis p. 641 - 646 (1996)
Update date:2022-07-30
Topics:
Dondoni, Alessandro
Merchan, Francisco L.
Merino, Pedro
Rojo, Isabel
Tejero, Tomas
A method is described for the enantioselective synthesis of 2-(1-aminoalkyl)thiazoles 6 via stereoselective alkylation of the carbanions of (+)-(R)-camphor and (-)-(1S, 2S, 5S)-2-hydroxypinan-3-one imines 2 and 3 derived from 2-(aminomethyl)thiazole (2-AMT, 1). Compounds 6 serve as α-amino aldehyde precursors via thiazolyl-to-formyl conversion.
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(1996)Doi:10.1016/0022-328X(96)06192-X
(1996)Doi:10.1039/p19960001205
(1996)Doi:10.1002/cber.19681010306
(1968)Doi:10.1021/jm980190c
(1998)Doi:10.1016/j.tetlet.2011.08.151
(2011)
