1,3-Asymmetric induction by planar chiral ( η4-diene) Fe( CO) 3 complexes in Diels-Alder reaction

DOI: 10.1016/0022-328X(95)06076-9

Source and publish data:

Journal of Organometallic Chemistry p. 99 - 101 (1996)

Update date:2022-07-30

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Authors:

Nakanishi, Saburo

Kumeta, Katsuhisa

Sawai, Yasuhiro

Takata, Toshikazu

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Article abstract of DOI:10.1016/0022-328X(95)06076-9

The Diels-Alder reaction of 1,3-dienes with α, β-unsaturated ketones adjacent to planar chiral (η⁴-1,3-diene)Fe(CO)₃ complexes in the presence of Lewis acid proceeded diastereoselectively. The dienophiles reacted with cyclopentadiene

Full text of DOI:10.1016/0022-328X(95)06076-9

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Product name:Fe(CO)3(C₆H₅(CH)4C(O)C₆H₈CH₃)

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