Metallation in connection with cross-coupling reactions. Coupling of hindered aryls for the synthesis of 4-phenylpyridines as part of Streptonigrin and Lavendamycin analogues

DOI: 10.1016/0022-328X(95)05979-Y

Source and publish data:

Journal of Organometallic Chemistry p. 25 - 36 (1996)

Update date:2022-08-03

Topics:

Authors:

Godard Godard

Rocca Rocca

Pomel Pomel

Thomas-Dit-Dumont

Rovera Rovera

Thaburet

Marsais Marsais

Queguiner

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Article abstract of DOI:10.1016/0022-328X(95)05979-Y

The synthesis of the C-D ring system of Streptonigrin and Lavendamycln alkaloid analogues by cross-coupling under Suzuki's conditions has been studied. Steric hindrance is the main problem. It has been solved either by using strong bases or working in a sealed tube under pressure.

Full text of DOI:10.1016/0022-328X(95)05979-Y

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