Acta Crystallographica, Section C: Crystal Structure Communications p. 1636 - 1638 (1996)
Update date:2022-07-29
Topics:
Otto
Roodt
The title compound, trans-[PtCl(CH3){As(C6H4CH3)3}2], is one of the few bis tertiary arsine complexes of platinum(II). The complex exhibits square-planar geometry with the two arsine ligands in a non-linear trans orientation with an As1-Pt-As2 bond angle of 175.66 (4)°. The large trans influence of the methyl substituent is manifested in the long Pt-Cl bond distance of 2.397 (3) angstroms.
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Doi:10.1016/0040-4039(96)00895-7
(1996)Doi:10.1021/jo960559a
(1996)Doi:10.1016/S0040-4039(96)02320-9
(1997)Doi:10.1016/0040-4020(96)00600-X
(1996)Doi:10.1016/0040-4039(96)01531-6
(1996)Doi:10.1016/0040-4039(96)01415-3
(1996)
