Platinum-Assisted Addition of Carbonyl-Stabilized Phosphorus Ylides to Pentafluorobenzonitrile and Acetonitrile to Give Platinum(II) Complexes Containing Iminophosphorane and/or N-Bonded β-Imino Phosphorus Ylide Ligands. Crystal and Molecular Structures o

DOI: 10.1021/ic951666a

Source and publish data:

Inorganic Chemistry p. 6592 - 6598 (1996)

Update date:2022-08-02

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Authors:

Vicente, José

Chicote, Maria Teresa

Beswick, Michael A.

De Arellano, M. Carmen Ramirez

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Article abstract of DOI:10.1021/ic951666a

PtCl₂ reacts with C₆F₅CN to give trans-[PtCl₂(NCC₆F₅)₂] (1) which, in turn, reacts with carbonyl-stabilized phosphorus ylides Ph₃P=CHR [R = C(O)Me, CO₂Et] t

Full text of DOI:10.1021/ic951666a

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Product name:trans-[PtCl₂(NH=C(C₆F₅)C(=PPh₃)CO₂Et)(NCC₆F₅)]

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