Synthesis and x-ray crystal structure of [Li(C4H8O)4] [Yb(NPh2)4]

DOI: 10.1016/0277-5387(96)00281-1

Source and publish data:

Polyhedron p. 345 - 347 (1997)

Update date:2022-09-26

Topics:

Authors:

Wong, Wai-Kwok

Zhang, Lilu

Xue, Feng

Mak, Thomas C.W.

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Article abstract of DOI:10.1016/0277-5387(96)00281-1

The interaction of Yb(NPh₂)₂Cl with one equivalent of Li[(CH₂) (CH₂)PPh₂] in tetrahydrofuran gave the unexpected dark red complex [Li(C₄H₈O)₄][Yb(NPh₂)₄] (1) in 30% yield. An X-ray diffraction study reveals that the lanthanide-amide ate complex is composed of a discrete cation [Li(C₄H₈O)₄]⁺ and a discrete homoleptic tetrahedral Yb-amide anion [Yb(NPh₂)₄]^-. Copyright

Full text of DOI:10.1016/0277-5387(96)00281-1

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Product name:Li(OC₄H₈)4⁽¹⁺⁾*Yb(N(C₆H₅)2)4^(1-) = [Li(OC₄H₈)4][Yb(N(C₆H₅)2)4]

Cas No:184828-68-0

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