Tetrahedron Letters p. 8237 - 8240 (1996)
Update date:2022-07-30
Topics:
Crowley
Percy
Stansfield
1-(N,N-diethylcarbamoyloxy-2-fluoro-2-(phenylsulfonyl)-ethene has been prepared and reacted with a variety of dienes to give fluorinated [4+2] cycloadducts. In contrast, the desulfonated equivalent 1-(N,N-diethylcarbamoyloxy)-2-fluoro-E-ethene reacts with cyclopentadiene alone, to give mixtures of [4+2] and [2+2] cycloadducts.
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Doi:10.1021/acs.orglett.5b03340
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