Tetrahedron Letters p. 1905 - 1908 (1998)
Update date:2022-07-29
Topics:
Sattelkau, Tim
Eilbracht, Peter
The one-pot combination of Claisen rearrangement of allyl vinyl ethers followed by an intramolecular hydroacylation catalysed by RhCl(cod)(dppe) is used as a key step in the synthesis of meso- dimethyl-1,4-dioxa-dispiro[4.2.4.2]tetradecan-10-one (12). The diastereospecific outcome of the reaction is discussed This product is a potential precursor in the synthesis of solavetivone.
View MoreContact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
Hangzhou Haiqiang Chemical Co.,Ltd.
Contact:+86-571-86960370
Address:Add: 5/F, Around Town North Road,No. 10, Hangzhou, Zhejiang,China
Contact:86-571-87758773
Address:Room604 ,6F, Block A1-3 Xixi Plaza,No. 588 Wenyi West RD, Hangzhou,310012, China
Golden Union Agrochemical Import and Export Co., Ltd.
Contact:86-755-23910527
Address:Room 1106, Tower 3A, Excellence Century Center, Futian District, Shenzhen, China
Weihao Chemtech (ChangZhou) Co., Ltd.(expird)
Contact:051989185693
Address:NO 217 huangshan Rd ,Changzhou
Doi:10.1021/ja01546a017
(1958)Doi:10.1016/S0960-894X(97)00014-0
(1997)Doi:10.1016/S0277-5387(96)00440-8
(1997)Doi:10.1016/S0040-4039(01)97415-5
(1971)Doi:10.1039/b417493n
(2005)Doi:10.1021/jo048482a
(2004)
