Tetrahedron Letters p. 1905 - 1908 (1998)
Update date:2022-07-29
Topics:
Sattelkau, Tim
Eilbracht, Peter
The one-pot combination of Claisen rearrangement of allyl vinyl ethers followed by an intramolecular hydroacylation catalysed by RhCl(cod)(dppe) is used as a key step in the synthesis of meso- dimethyl-1,4-dioxa-dispiro[4.2.4.2]tetradecan-10-one (12). The diastereospecific outcome of the reaction is discussed This product is a potential precursor in the synthesis of solavetivone.
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