Radical cyclisation with high diastereofacial selectivity: Asymmetric synthesis of (+)-12b-epidevinylantirhine

DOI: 10.1039/a700834a

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 991 - 992 (1997)

Update date:2022-08-03

Topics:

Authors:

Ihara, Masataka

Katsumata, Akira

Fukumoto, Keiichiro

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Article abstract of DOI:10.1039/a700834a

Radical cyclisation of the chiral α,β-unsaturated ester 1, carried out in the presence of MAD, gives six-membered cyclic acetal 2 diastereoselectively, which is transformed into (+)-12b-epidevinylantirhine 7.

Full text of DOI:10.1039/a700834a

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