Tetrahedron p. 1215 - 1230 (1991)
Update date:2022-07-30
Topics: Total synthesis Hydrolysis Optically pure Cyclization Stereoselective Chiral Resolution Enzyme Catalysis Enzymatic Hydrolysis Cyclopropanes
Grandjean, D.
Pale, P.
Chuche, J.
Enzymatic hydrolysis of cis-1,2-bis(butyryloxymethyl)cyclopropane 3 under optimized conditions gives, in quantitative yield, optically pure cis-(1S,2R)-1-hydroxymethyl-2-butyryloxymethylcyclopropane 1.This compound is a versatile cyclopropane synthon as exemplified by the total synthesis of optically pure seaweed pheromones Dictyopterenes A and C'.
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