Anodically induced cycloaddition of vinylethylether to N-Cyanomethyl-Oxazolidine system. Stereoselective synthesis of β-amino ketal compounds

DOI: 10.1016/S0040-4039(97)00827-7

Source and publish data:

Tetrahedron Letters p. 4075 - 4078 (1997)

Update date:2022-08-03

Topics:

Authors:

Martens, Thierry

Billon-Souquet, Florence

Gauthier, Isabelle

Royer, Jacques

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Article abstract of DOI:10.1016/S0040-4039(97)00827-7

The anodic oxidation of N-cyanomethyloxazolidine system 1 initiates an electrocatalytic cycloaddition of vinylethylether at the N,O acetal function and affords, after NaBH₄ reduction and acid hydrolysis, the corresponding enantiomeric pure bicyclic ketal 4.

Full text of DOI:10.1016/S0040-4039(97)00827-7

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