Tetrahedron p. 11203 - 11210 (1997)
Update date:2022-09-26
Topics:
Chackalamannil, Samuel
Wang, Yuguang
The synthesis of (S)-2-methyl tetrahydropyridine-N-oxide (4), a key intermediate for the enantioselective construction of trans-2,6-disubstituted piperidines via [3+2] nitrone cycloaddition reaction, is described. Nitrone 4 was elaborated to the fire ant venom alkaloid (+)-solenopsin-A (2) via intermediate 14.
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