Formation of quaternary centres via iron allyl cations. Rapid entry into spirocyclic ring systems

DOI: 10.1139/v97-116

Source and publish data:

Canadian Journal of Chemistry p. 965 - 974 (1997)

Update date:2022-08-05

Topics:

Authors:

Charlton, M. Anne

Green, James R.

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Article abstract of DOI:10.1139/v97-116

Ester-substituted allyltetracarbonyliron cations react with cycloalkylidene-type silyl enol ethers, silyl ketene acetals, and β-keto- esters to give 1,6-dicarbonyl compounds containing a newly formed quaternary centre. Selected condensation products are c

Full text of DOI:10.1139/v97-116

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