Complexes of yttrium and lanthanide perchlorates with 4-N-(2′-furfurylidene)aminoantipyrine

Article abstract of DOI:10.1080/00945719708000162

Yttrium and lanthanide perchlorate complexes with 4-N-(2′-furfurylidene)aminoantipyrine (FAA) of the composition [Ln(FAA)₃(CIO₄)₂]ClO₄ (where Ln = Y, La, Pr, Nd, Sm, Eu, Gd, Dy, Ho, and Er) have been synthesised and characterized by elemental analyses, molar conductance in non-aqueous solvents, magnetic susceptibility measurements, infrared, electronic as well as proton NMR spectra and thermogravimetric analyses. In these complexes the ligand FAA acts as a neutral tridentate one coordinating through the carbonyl oxygen, azomethine nitrogen and oxygen of the furan ring. Two of the perchlorate ions are coordinated monodentately and the third one being ionic.

Full text of DOI:10.1080/00945719708000162

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Synthesis and Reactivity in
Inorganic and Metal-Organic
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Complexes of Yttrium
and Lanthanide
Perchlorates with 4-N-(2′-
Furfurylidene)aminoantipyrine
C. R. Vinodkumar a & P. K. Radhakrishnan a
a School of Chemical Sciences , Mahatma Gandhi
University Kottayam , 686 560, Kerala, India
Published online: 22 Aug 2006.
To cite this article: C. R. Vinodkumar & P. K. Radhakrishnan (1997) Complexes of
Yttrium and Lanthanide Perchlorates with 4-N-(2′-Furfurylidene)aminoantipyrine,
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27:9, 1347-1355,
DOI: 10.1080/00945719708000162
To link to this article: http://dx.doi.org/10.1080/00945719708000162
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