Asymmetric Cyclopropanation of Allylic Ethers: Cleavage and Regeneration of the Chiral Auxiliary

DOI: 10.1021/jo00056a028

Source and publish data:

Journal of Organic Chemistry p. 933 - 936 (1993)

Update date:2022-08-03

Topics:

Authors:

Charette, Andre B.

Cote, Bernard

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Article abstract of DOI:10.1021/jo00056a028

The ring contraction reaction of 2-O-<<(trifluoromethyl)sulfonyl>oxy>-β-D-glucopyranosides and their corresponding α-anomers is reported.The rearrangement was shown to occur under extremely mild basic conditions to allow isolation of acid-sensitive optica

Full text of DOI:10.1021/jo00056a028

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