Stereoselective alkenylation of aldehydes with phosphorus carbanions: Preparation of E- and Z-2-alkoxy- and 2-aryloxy-2-alkenoates

DOI: 10.1016/S0040-4020(97)10149-1

Source and publish data:

Tetrahedron p. 17097 - 17114 (1997)

Update date:2022-07-29

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Authors:

Seneci, Pierfausto

Leger, Isabelle

Souchet, Michel

Nadler, Guy

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Article abstract of DOI:10.1016/S0040-4020(97)10149-1

Eighteen phosphorus-based alkenylation reagents 1a-6c were synthesized and condensed with n-butyraldehyde 7a and benzaldehyde 7f. They were condensed with the aldehydes 7b-e,g-n to produce 2-methoxy-2-alkenoates 8a-n and 2-phenoxy-2-alkenoates 9a-n. A dis

Full text of DOI:10.1016/S0040-4020(97)10149-1

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