Canadian Journal of Chemistry p. 1331 - 1335 (1997)
Update date:2022-08-03
Topics: NMR spectroscopy Nucleophilic Aromatic Substitution Gas Chromatography High-performance liquid chromatography
Ross, Joseph P.
Couture, Philippe
Warkentin, John
Dimethoxycarbene, generated at 110°C by thermolysis of 2,2-dimethoxy-5,5-dimethyl-Δ3-1,3,4-oxadiazoline, displaces fluoride from aromatic rings that are activated with electron-withdrawing groups. Intermolecular substitution on Sanger's reagent and on hexafluorobenzene are reported, together with intramolecular substitution by a dioxycarbene with a tethered aryl group.
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Doi:10.1016/S0022-328X(00)92642-1
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(1998)Doi:10.1081/SCC-120026336
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