Journal of Organometallic Chemistry p. 249 - 255 (1997)
Update date:2022-08-03
Topics:
Baker
Kloo, Lars A.
Rickard, Clifton E.F.
Taylor, Michael J.
Adducts Ph3PGaI3 and Ph3AsGaI3 obtained by adding the ligands to Et2OGaI3 have been investigated by 71Ga NMR, IR/Raman spectroscopy and X-ray diffraction, Et2OInI3 with Ph3P gives (Ph3P)3(InI3)2. Ph3As yields (Ph3As)3(InI3)2 · H2O as rhombohedral crystals whose structure was solved by X-ray diffraction. Both these indium complexes contain Ph3EInI3 molecules alongside five-coordinate aclducts (Ph3E)2InI3 with the Ph3E ligands attached in axial sites by long and unequal bonds to a planar InI3 unit. Vibrational assignments are made for Ph3PGaI3, Ph3AsGaI3, Ph3EInI3 and (Ph3E)2InI3 (E = P or As).
Contact:+8613400661290
Address:No 908,Kangwan Rd, Liuyang Economic
Shanghai Yuanding Chem. Sci. & Tech. Co., Ltd.
website:http://www.shydtec.com
Contact:86-21-57721279
Address:Science and Technology Park, Songjiang District, Shanghai, China
Suzhou BEC Fine Chemicals Co., Ltd.
website:http://www.bek.com.cn
Contact:0512-68095917 18913193865
Address:6, Jin Shan Road, Suzhou New District, 215011 China Suzhou Nations Pharmaceutical Innovation Center Inside
Nanjing Qirui Material Co., Ltd.
Contact:+86-25-52320053
Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Doi:10.1021/ol071098q
(2007)Doi:10.1016/S0040-4020(01)92606-7
(1968)Doi:10.1021/ie50524a043
(1953)Doi:10.1002/chem.201805878
(2019)Doi:10.1016/S0960-894X(97)10198-6
(1998)Doi:10.1016/j.tet.2008.12.052
(2009)
