Tetrahedron p. 11925 - 11934 (1998)
Update date:2022-08-03
Topics:
Kulcitki, Veaceslav
Ungur, Nicon
Vlad, Pavel F.
The superacidic cyclization of aliphatic and partially cyclized C10- C20 terpenylphenylsulfones proceeds structure-selectively and stereospecifically, affording α- or mixtures of α- and γ-isomers of completely cyclized terpenylphenylsulfones. The configuration of the phenylsuffonylmethylene group in the cyclized products is predetermined by the configuration of the allylic double bond in the starting compounds.
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(1998)
