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Non-linear Optical Materials containing Molybdenum or Tungsten Mononitrosyl Redox Centres: Diaromatic Azo Derivatives

DOI: 10.1039/DT9940003427

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3427 - 3440 (1994)

Update date:2022-08-03

Topics:

Authors:

Coe, Benjamin J.Coe, Benjamin J.

Foulon, Jean-DominicFoulon, Jean-Dominic

Hamor, Thomas A.Hamor, Thomas A.

Jones, Christopher J.Jones, Christopher J.

McCleverty, Jon A.McCleverty, Jon A.

et al.et al.

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Article abstract of DOI:10.1039/DT9940003427

The following compounds have been prepared: >(2-n)> 5-C5H4)Fe(ν5-C5H5), E = O, R = R' = H, M = Mo, X = Cl or I, n = 0 or 1; E = NH, R = R' = H, n = 1, M = Mo or W, X = Cl; E = NH, R = Me, R' = H, n = 1, M = Mo, X = F, Cl, Br, I or OC6H11; M = W, X = Cl; E = NH, R = R' = Me, n = 1, M = Mo, X = Cl or I; M = W, X = Cl; R = NMe2, E = O, R = R' = H, M = Mo, X = Cl or I, n = 0 or 1; M = W, X = Cl, n = 1; E = NH, R = R' = H, n = 1, M = Mo, X = Cl or I; M = W, X = Cl>, >> (M = Mo, X = Cl or I; M = W, X = Cl) and >-4)>.Several of the ferrocenyl derivatives have been found to produce frequency doubling of radiation at 1907 nm, whereas the derivatives containing NMe2 or OEt groups do not.A single-crystal X-ray diffraction study has shown that -4>>*CH2Cl2 crystallises in the space group P21 and is isostructural with its molybdenum counterpart; in these crystals the molecules appear to be favourably oriented to produce phase matching.

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Product name:4-amino-4'-ferrocenyl-2,3'-dimethylazobenzene

Cas No:220082-14-4

220082-14-4

R&D Labs maybe for 220082-14-4

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