New skeletal rearrangements of C and D rings of a 13-oxobaccatin III derivative

DOI: 10.1016/S0040-4020(98)00993-4

Source and publish data:

Tetrahedron p. 15833 - 15844 (1998)

Update date:2022-08-02

Topics:

Authors:

Marder-Karsenti, Raphaele

Dubois, Joelle

Chiaroni, Angele

Riche, Claude

Guenard, Daniel

Gueritte, Francoise

Potier, Pierre

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Article abstract of DOI:10.1016/S0040-4020(98)00993-4

13-Oxobaccatin II (4) was oxidized to 7,13-dioxo D-secobaccatin III (5). This compound, when treated with base or cyanide ion, underwent rearrangements involving the rupture of the C-7,C-8 bond, the migration of the benzoyl and acetyl groups and intramole

Full text of DOI:10.1016/S0040-4020(98)00993-4

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