Tetrahedron Letters p. 5095 - 5098 (1999)
Update date:2022-08-02
Topics: Intramolecular Starting Materials Preparation Homolytic substitution Samarium(II) iodide Selenium Pentose
Schiesser, Carl H.
Zheng, Shi-Long
Treatment of 2,3,4-tri-O-benzyl-5-benzylseleno-5-deoxyribose (9) with samarium(II) iodide in THF affords 2,3,4-tri-O-benzyl-5-deoxy-5-seleno-D- ribopyranose (10) in 50% isolated yield in a process most likely involving intramolecular homolytic substitutio
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