Bulletin of the Chemical Society of Japan p. 1671 - 1674 (1981)
Update date:2022-08-02
Topics:
Fujishima, Akira
Kato, Tamihiko
Maekawa, Etsuro
Honda, Kenichi
Current doubling mechanism of the photoanodic reaction of sodium formate at the ZnO electrode is re-examined.Quantitative analysis of the reaction products revealed that ZnO electrode corroded during the current doubling reaction, which has not been previously reported.However, zinc ions were formed with about 50percent of current efficiency.Carbon dioxide, instead of oxygen, was formed during the reaction.These experimental observations strongly suggested mechanism proposed by earlier workers were incorrect.A new mechanism is proposed.
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