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104-55-2

Basic Information
CAS No.: 104-55-2
Name: Cinnamaldehyde
Molecular Structure:
Molecular Structure of 104-55-2 (Cinnamaldehyde)
Formula: C9H8O
Molecular Weight: 132.1592
Synonyms: 2-Propenal,3-phenyl-;3-Phenyl-2-propen-1-al;3-Phenyl-2-propenal;3-Phenyl-2-propenaldehyde;3-Phenyl-2-propene-1-al;3-Phenylacrolein;3-Phenylacrylaldehyde;3-Phenylpropenal;Abion CA;Benzylideneacetaldehyde;Cassia aldehyde;Cinnacure;Cinnamal;Cinnamic aldehyde;Cinnamite;Cinnamyl aldehyde;NSC16935;NSC 40346;Phenylacrolein;Zimtaldehyde;b-Phenylacrolein;Cinnamaldehyde/cinnamic aldehyde;
EINECS: 203-213-9
Density: 1.034 g/cm3
Melting Point: -9 - -4 °C(lit.)
Boiling Point: 246.8 °C at 760 mmHg
Flash Point: 71.1 °C
Solubility: slightly soluble in water
Appearance: yellow liquid with an odour of cinnamon
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38-43
Safety: 26-36/37
Transport Information:
PSA: 17.07000
LogP: 1.89870
Synthetic route
104-54-1

3-Phenylpropenol

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With dimethyl selenoxide In dichloromethane for 7h; Heating;100%
With 2,2'-bipyridylchromium peroxide In benzene for 1.25h; Heating;100%
With tert.-butylhydroperoxide; polystyrene-bound phenylselenic acid In tetrachloromethane for 63h; Heating;100%
26958-41-8

cinnamyl-1,3-dithiane

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With ammonium iodide; dihydrogen peroxide; sodium dodecyl-sulfate In water at 20℃; for 1h; micellar medium;100%
With dimethyl sulfoxide at 20℃; for 1h; Reagent/catalyst; Solvent;94%
With dihydrogen peroxide; iodine; sodium dodecyl-sulfate In water at 20℃; for 1h; Micellar solution;92%
7148-78-9

3,3-diethoxyl-1-phenylprop-1-ene

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With water at 20℃; for 2h;100%
With boron trifluoride diethyl etherate; tetraethylammonium iodide In chloroform for 2h; Heating;81%
With sulfuric acid In nitromethane for 48h; Ambient temperature; Yield given;
83977-12-2, 5660-60-6

2-((E)-Styryl)-[1,3]dioxolane

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With water at 20℃; for 2h;100%
With n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 1h; Heating;97%
With tetrachlorosilane In dichloromethane at 20℃; for 0.25h;96%
4407-36-7

(2E)-3-phenyl-2-propen-1-ol

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With iodosylbenzene; 4 A molecular sieve; sodium ruthenate(VI) In dichloromethane at 20℃; for 3h; Oxidation;100%
With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 1-ethyl-3-methylimidazolium hexafluorophosphate In dichloromethane at 20℃; for 1h;95%
With N-Bromosuccinimide; β‐cyclodextrin In methanol; water; acetone at 20℃; for 8h;94%
104-53-0

3-phenyl-propionaldehyde

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With (2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 1h;100%
With bis(benzonitrile)palladium(II) dichloride; tert.-butylnitrite; oxygen; toluene-4-sulfonic acid; 1,3,5-trimethyl-benzene In tert-butyl alcohol at 25℃; under 760.051 Torr; for 7h;94%
With manganese(IV) oxide; benzyl-methyl-amine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In tetrahydrofuran at 20℃; for 6h; Reagent/catalyst; Solvent;78%
4364-06-1

cinnamaldehyde dimethylacetal

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With water at 20℃; for 2h;100%
With iron(III) p-toluenesulfonate hexahydrate In water at 20℃; for 4h;96%
61912-03-6

2-hydroxy-4-phenyl-3-butenenitrile

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With (η(6)-benzene)chloro[1,2-bis(diphenylphosphino)ethane]ruthenium(II) chloride In benzene at 120℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;100%
4360-47-8

cinnamonitrile

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With potassium carbonate In water; dimethyl sulfoxide at 60℃; for 6h; High pressure; Green chemistry;99.9%
With formic acid; platinum(IV) oxide In water at 55 - 60℃; for 20h;56%
37973-54-9, 64847-78-5

1,1-diacetoxy-3-phenylprop-2-ene

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tin(ll) chloride In acetonitrile at 25℃; for 0.0333333h; Hydrolysis;99%
With pyrographite In dichloromethane for 0.25h; Heating;98%
With iron(II) sulfate In dichloromethane for 0.25h; Heating;98%
591-50-4

iodobenzene

81925-30-6, 149538-53-4, 219726-39-3

(E)-3-(tri-n-butylstannyl)-2-propenal

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With Pd-NHC star polymer P3 In d7-N,N-dimethylformamide at 20℃; for 19h; Stille Cross-Coupling (Migita-Kosugi-Stille Coupling);99%
68498-19-1

2-styryl-benzo[1,3]dithiole

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tetrafluoroboric acid; mercury(II) oxide In tetrahydrofuran for 5h; Ambient temperature;98%
13372-81-1

cinnamaldoxime

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With 1H-imidazole; [bis(acetoxy)iodo]benzene; Cu(AAOPD) In acetonitrile at 20℃; for 0.166667h;98%
With benzyltriphenylphosphonium dichromate In acetonitrile for 0.333333h; Oxidation; Heating;97%
With 1,4-dibenzyl-1,4-diazoniabicyclo[2.2.2]octane chlorochromate In acetonitrile for 0.25h; Heating;95%
109283-53-6, 141427-94-3, 18042-41-6

trimethylsilyl cinnamyl ether

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With n-butyltriphenylphosphonium peroxodisulfate In acetonitrile for 0.166667h; Heating;98%
With manganese(IV) oxide; aluminium trichloride In acetonitrile for 0.25h; Oxidation; Heating;93%
With N-benzyl-N,N-dimethyl anilinium peroxodisulfate In acetonitrile for 0.116667h; Reflux;93%

5,5-Dimethyl-2-((E)-styryl)-[1,3]dioxane

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With sodium perborate In acetic acid at 25℃; for 8h;98%
With iron(III) p-toluenesulfonate hexahydrate In water for 1h; Reflux;74%
With water at 80℃; for 24h;17%
80563-94-6

2-styryl-1,3-oxathiolane

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With N-Bromosuccinimide; water In acetone at 20℃; for 1.66667h; Hydrolysis;98%
With Glyoxilic acid; Amberlyst 15 for 0.025h; microwave irradiation;93%
Stage #1: 2-styryl-1,3-oxathiolane In ethanol at 20℃;
Stage #2: With water In ethanol at 20℃;
86%
5663-34-3

2-((E)-Styryl)-[1,3]dioxane

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With iron(III) chloride hexahydrate; acetaldehyde In dichloromethane at 20℃; for 0.25h;98%
99441-44-8, 80356-15-6

3-phenyl-2-propenyl tetrahydro-2H-pyran-2-yl ether

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With chromium(VI) oxide; HZSM-5 zeolite for 0.0166667h; microwave irradiation;95%
With aluminium trichloride; tetramethylammonium chlorochromate In acetonitrile for 0.916667h; Heating;92%
With zinc dichromate(VI) at 20℃;90%

1,1-dipropionyloxy-3-phenylprop-2-ene

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tetra-N-butylammonium tribromide In methanol at 20℃; for 0.4h;95%

1,1-diisobutyryloxy-3-phenylprop-2-ene

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tetra-N-butylammonium tribromide In methanol at 20℃; for 1h;95%
104-54-1

3-Phenylpropenol

A

122-97-4

3-Phenyl-1-propanol

B

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With oxygen; potassium hydroxide In chloroform; water at 10℃; under 760.051 Torr; for 8h;A 5%
B 95%
With C28H37ClOOsP2; oxygen In toluene at 120℃; under 760.051 Torr; for 24h;
With phosphinito complex of palladium(II) In N,N-dimethyl-formamide at 80℃; for 24h;A 6 %Spectr.
B 24 %Spectr.
2687-12-9

cinnamyl chloride

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With 1-dodecyl-3-methylimidazolium iron chloride; periodic acid at 30℃; for 2h;94%
With water; sodium hydroxide at 20℃; for 0.0833333h; Microwave irradiation;87%
With sodium periodate In dichloromethane at 40 - 50℃; Ionic liquid;85%
With trimethylamine-N-oxide In dichloromethane; dimethyl sulfoxide for 6h; -20 deg C to r.t.;60%
Multi-step reaction with 2 steps
1: 88 percent / dimethylformamide
2: 1.) PdCl2, NaCl, NaOAc; 2.) O2 / 1.) AcOH, reflux; 2.) CH3CN, irradiation λ=366 nm
View Scheme
5616-58-0

2-styryl-1,3-dithiolane

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With thionyl chloride; dihydrogen peroxide In acetonitrile at 25℃; for 0.0166667h;93%
With silica gel In neat (no solvent) at 20℃; for 0.05h;92%
With oxygen; 2,4,6-tris(p-chlorophenyl)pyrylium perchlorate In dichloromethane for 1h; Irradiation;41%
59336-59-3

cinnamaldehyde oxime

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With quinolinium dichromate(VI) In acetonitrile for 1.5h; Heating;93%
With water In acetone for 0.025h; microwave irradiation;93%
With silica gel; iron(III) chloride for 0.00833333h; microwave irradiation;90%
4187-87-5

1-Phenyl-2-propyn-1-ol

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
toluene-4-sulfonic acid; tetrabutylammonium perrhenate In dichloromethane for 2h; Ambient temperature;92%
With [Ag{μ2-N,S-(1,3,5-triaza-7-phosphaadamantane)=NP(=S)(OEt)2}]x[SbF6]x In water at 160℃; for 5h; Microwave irradiation;91%
With methanesulfonic acid; iron(II) chloride tetrahydrate In 1,2-dichloro-ethane at 60℃; for 3h; Meyer-Schuster Rearrangement;90%
637-50-3

1-phenylpropene

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With tert.-butylhydroperoxide; Ru(2,4,13,15-tetraphenyl-1,5,12,16-tetraaza-tricyclo[14.2.2.06,11]eicosa-4,6(11),7,9,12-pentaene)Cl2 In acetonitrile at 20℃; for 3h; Reagent/catalyst; Irradiation;92%
With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane; water Ambient temperature; Yield given;
3839-82-5

cinnamaldehyde semicarbazone

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With NTPPPODS In water; acetonitrile for 0.416667h; Reflux;92%
With bismuth(III) chloride; benzyltriphenylphosphonium peroxymonosulfate In acetonitrile for 2h; Heating;75%
With aluminium trichloride; benzyltriphenylphosphonium chlorochromate In acetonitrile for 1.5h; Heating;75%
(α-styryl)(ethoxy)carbene chromium pentacarbonyl

(α-styryl)(ethoxy)carbene chromium pentacarbonyl

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With hexamethylenetetramine; water In tetrahydrofuran at 20℃; for 24h;92%
21737-13-3

(E)-styrylaldehyde oxime

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
With aluminium trichloride; 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate at 20℃; for 0.00722222h;92%
With 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane dichromate In dichloromethane for 0.00722222h; Irradiation;92%
141-84-4

2-thioxo-4-thiazolidinone

104-55-2

3-phenyl-propenal

15328-87-7

5-(3-phenyl-allylidene)-2-thioxo-thiazolidin-4-on e

Conditions
ConditionsYield
With ammonium acetate; acetic acid In toluene Reflux;100%
With thiourea; urea at 110℃; for 0.1h; Knoevenagel condensation; Neat (no solvent);91%
With sodium hydroxide
104-94-9

4-methoxy-aniline

104-55-2

3-phenyl-propenal

Conditions
ConditionsYield
piperidine In ethanol for 5h; Heating;100%
With magnesium sulfate In dichloromethane at 20℃;100%
In ethyl 2-hydroxypropionate; water at 20℃; for 0.025h;96%
100-65-2

N-Phenylhydroxylamine

104-55-2

3-phenyl-propenal

37056-75-0, 1070670-27-7

cinnamaldehyde-(N-phenyl oxime )

Conditions
ConditionsYield
In chloroform at 0℃;100%
In water Ambient temperature;93%
107-15-3

ethylenediamine

104-55-2

3-phenyl-propenal

3080-97-5

N,N'-bis(styrylmethylene)ethane-1,2-diamine

Conditions
ConditionsYield
In ethanol for 1h; Condensation; Heating;100%
With sodium hydrogen sulfate; silica gel for 0.0333333h; microwave irradiation;89%
In ethanol Reflux; Inert atmosphere; Schlenk technique;78%
62-53-3

aniline

104-55-2

3-phenyl-propenal

953-21-9

N-(3-phenylallylidene)benzenamine

Conditions
ConditionsYield
With zirconocene dichloride In dichloromethane at 40℃; Schlenk technique; Inert atmosphere;100%
With magnesium sulfate In dichloromethane at 20℃;100%
In ethyl 2-hydroxypropionate; water at 20℃; for 0.0666667h;98%
563-41-7

semicarbazide hydrochloride

104-55-2

3-phenyl-propenal

3839-82-5

cinnamaldehyde semicarbazone

Conditions
ConditionsYield
With acetic acid In water for 0.5h; Reflux;100%
With aluminum oxide In water; tert-butyl alcohol for 0.0833333h;90%
With ethanol
In ethanol
104-55-2

3-phenyl-propenal

98-86-2

acetophenone

Conditions
ConditionsYield
Stage #1: acetophenone With sodium hydroxide In ethanol; water at 0 - 5℃;
Stage #2: 3-phenyl-propenal In ethanol; water
100%
With poly(N-vinylimidazole) In neat (no solvent) at 20℃; for 0.666667h; Aldol Condensation; Sonication; Green chemistry;92%
With sodium hydroxide In ethanol; water90%
104-55-2

3-phenyl-propenal

104-53-0

3-phenyl-propionaldehyde

Conditions
ConditionsYield
With formic acid; 3,7-dimethyl10-p-tolyl-5-deazaflavins at 120℃; for 25h;100%
With tri-n-butyl-tin hydride; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran Ambient temperature;99%
With 0.42C23H20N4O4*2Cl(1-)*Zn(2+)*10.16H2O*0.58Pd(2+)*0.58C23H20N4O4(1-); hydrogen In tetrahydrofuran at 20℃; under 760.051 Torr; for 1h;99%
104-55-2

3-phenyl-propenal

104-54-1

3-Phenylpropenol

Conditions
ConditionsYield
With diphenylsilane; cesium fluoride at 25℃; for 0.05h;100%
With C28H28Cl2N4Pd; hydrogen In methanol at 30 - 35℃; under 760.051 Torr; for 8h; chemoselective reaction;100%
With C8H15BN2OS2; scandium tris(trifluoromethanesulfonate) In dichloromethane at 20℃; Reagent/catalyst; Schlenk technique; Inert atmosphere;100%
108-24-7

acetic anhydride

104-55-2

3-phenyl-propenal

Acetic acid 1-phenylsulfanylmethyl-but-2-ynyl ester

Conditions
ConditionsYield
With pyridine; dmap100%
20948-67-8

5-chloro-1H-indole-2-carbohydrazide

104-55-2

3-phenyl-propenal

97132-94-0

5-Chlor-N'-(styrylmethylen)-2-indolcarbohydrazid

Conditions
ConditionsYield
In ethanol for 3h; Heating;100%
107-21-1

ethylene glycol

104-55-2

3-phenyl-propenal

83977-12-2, 5660-60-6

2-((E)-Styryl)-[1,3]dioxolane

Conditions
ConditionsYield
aluminum oxide In tetrachloromethane for 24h; Heating;100%
With natural kaolinitic clay In benzene for 2h; Heating;93%
With cationite KU-2 (H+) In water; benzene at 80℃; Dean-Stark;90%
79-19-6

thiosemicarbazide

104-55-2

3-phenyl-propenal

5351-70-2

cinnamaldehyde thiosemicarbazone

Conditions
ConditionsYield
With acetic acid In water for 0.5h; Reflux;100%
In methanol90%
With hydrogenchloride In ethanol at 20℃; for 3h;90%
109-80-8

1.3-propanedithiol

104-55-2

3-phenyl-propenal

26958-41-8

cinnamyl-1,3-dithiane

Conditions
ConditionsYield
With thionyl chloride; silica gel In benzene at 20℃; for 5h;100%
tellurium tetrachloride In 1,2-dichloro-ethane for 3h; Ambient temperature;99%
With lithium trifluoromethanesulfonate at 90℃; for 0.0833333h; Alkylation;98%
420-90-6

3-bromo-3,3-difluropropene

104-55-2

3-phenyl-propenal

88257-89-0

4,4-difluoro-1-phenylhexa-1,5-dien-3-ol

Conditions
ConditionsYield
With indium In water at 20℃; for 3h; Addition;100%
With zinc In tetrahydrofuran 1.) 0 deg C to RT, 4.5 h; 2.) RT, overnight;74%
105192-15-2

3-(benzimidazol-2-ylmethyl)thiazolidine-2,4-dione

104-55-2

3-phenyl-propenal

105192-22-1

3-(1H-Benzoimidazol-2-ylmethyl)-5-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-thiazolidine-2,4-dione

Conditions
ConditionsYield
With sodium acetate In acetic acid for 12h; Heating;100%
104-55-2

3-phenyl-propenal

100-63-0

phenylhydrazine

1216-15-5

cinnamaldehyde phenylhydrazone

Conditions
ConditionsYield
piperidine In ethanol for 5h; Heating;100%
With oxidized single-walled carbon nanotubes(SWCNs-COOH) In ethanol at 80℃; for 0.75h;98%
With Dowex resin acid form In ethanol for 0.75h;88%
104-55-2

3-phenyl-propenal

1-methyl-1-aminoguanidinium iodide

N-Diaminomethylene-N-methyl-N'-[(E)-3-phenyl-prop-2-en-(E)-ylidene]-diazenium; iodide

Conditions
ConditionsYield
In methanol at 20℃; for 336h;100%
104-55-2

3-phenyl-propenal

100-46-9

benzylamine

77499-86-6, 99333-56-9, 119353-37-6, 60293-41-6

1-benzyl-4-phenyl-1-aza-1,3-butadiene

Conditions
ConditionsYield
With magnesium sulfate In dichloromethane at 20℃; for 6h; Schlenk technique; Inert atmosphere;100%
With 1-butyl-3-methylimidazolium Tetrafluoroborate In neat (no solvent) at 60℃; for 2h; Reagent/catalyst; Inert atmosphere; Electrolysis;95%
In methanol at 20℃; Molecular sieve;79%
104-55-2

3-phenyl-propenal

105-34-0

methyl 2-cyanoacetate

85620-43-5

2-cyano-5-phenyl-2,4-pentadien carboxylic acid methyl ester

Conditions
ConditionsYield
aluminum oxide for 0.05h; Ambient temperature;100%
With diammonium phosphate In water at 20℃; Knoevenagel condensation;90%
With Porcine Pancreas Lipase In water; tert-butyl alcohol at 40℃; for 120h; Knoevenagel Condensation; Enzymatic reaction; stereoselective reaction;89%
With aluminum oxide; ammonium acetate for 0.0333333h; Knoevenagel condensation; microwave irradiation (850 watt);70%
104-55-2

3-phenyl-propenal

18365-42-9

α-chloro-cinnamaldehyde

Conditions
ConditionsYield
With pyridine; Phenylselenyl chloride In dichloromethane at 37℃; for 96h;100%
Multi-step reaction with 2 steps
1: chloroform; chlorine
2: glacial acetic acid; potassium acetate
View Scheme
Multi-step reaction with 2 steps
1: carbon tetrachloride; chlorine / -5 °C
2: aqueous sodium acetate
View Scheme
100-52-7

benzaldehyde

104-55-2

3-phenyl-propenal

83977-12-2, 5660-60-6

2-((E)-Styryl)-[1,3]dioxolane

Conditions
ConditionsYield
With monoaluminum phosphate In acetonitrile for 1.5h; Heating;100%
104-55-2

3-phenyl-propenal

4407-36-7

(2E)-3-phenyl-2-propen-1-ol

A

84-15-1

o-terphenyl

B

106536-22-5

3,3-bis(3-phenyl-2-propen-1-yl)pentane-2,4-dione

C

C18H16

Conditions
ConditionsYield
With triphenylphosphine; palladium(II) acetylacetonate In 1,4-dioxane for 91h; Heating;A 43%
B 100%
C n/a
With triphenylphosphine; palladium(II) acetylacetonate In 1,4-dioxane for 24h; Heating;A 16%
B 89%
C 37%
104-55-2

3-phenyl-propenal

lithium tetrabutylindate

lithium tetrabutylindate

20157-19-1

1-phenyl-1-hepten-3-ol

Conditions
ConditionsYield
for 2h; Ambient temperature;100%
104-55-2

3-phenyl-propenal

60-24-2

2-hydroxyethanethiol

80563-94-6

2-styryl-1,3-oxathiolane

Conditions
ConditionsYield
With PPA; silica gel In 1,2-dichloro-ethane at 20℃; for 0.5h;100%
TiCl4 on montmorillonite In dichloromethane for 1h; Heating;95%
bis(acetylacetonato)dioxidomolybdenum(VI) In acetonitrile at 20℃; for 3.5h;92%
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    104-55-2

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    104-55-2

    Cinnamic aldehyde 104-55-2 Direct Manufacturer

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    BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

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  • High quality Cinnamic Aldehyde  supplier in China

  • Casno:

    104-55-2

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  • China Manufacturer Supply Cinnamaldehyde  CAS 104-55-2

  • Casno:

    104-55-2

    China Manufacturer Supply Cinnamaldehyde CAS 104-55-2

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  • Cinnamaldehyde, Cinnamic aldehyde, CAS: 104-55-2, 3-Phenyl-2-Propenal

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    104-55-2

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  • 104-55-2  Cinnamaldehyde

  • Casno:

    104-55-2

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  • Cinnamaldehyde

  • Casno:

    104-55-2

    Cinnamaldehyde

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  • Casno:

    104-55-2

    Cinnamaldehyde CAS 104-55-2

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    Cinnamic aldehyde CAS 104-55-2 is an organic compound with the formula C6H5CH=CHCHO. Ooccurring as both cis- and trans isomers, it gives cinnamon its flavor and odor. This pale yellow, viscous liquid occurs in the bark of cinnamon trees and other s

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  • Cinnamaldehyde

  • Casno:

    104-55-2

    Cinnamaldehyde

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  • (E)-3-phenyl-2-propenal

  • Casno:

    104-55-2

    (E)-3-phenyl-2-propenal

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  • Cinnamaldehyde

  • Casno:

    104-55-2

    Cinnamaldehyde

    Min.Order: 5 Milligram

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  • Cinnamaldehyde

  • Casno:

    104-55-2

    Cinnamaldehyde

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  • Casno:

    104-55-2

    Cinnamaldehyde CAS: 104-55-2

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    Product Name Cinnamaldehyde Synonyms Cinnamic aldehyde CAS No. 104-55-2 Molecular weight

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  • Cinnamaldehyde/high quality/best price

  • Casno:

    104-55-2

    MSDS/COA Download

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  • Factory Supply  Cinnamaldehyde

  • Casno:

    104-55-2

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    ProName: Cinnamaldehyde CAS 104-55-2 CasNo: 104-55-2 Molecular Formula: C9H8O Appearance: Unique scent, colorless or Light yello... Application: In flavors and fragrances,oil and gas ... DeliveryTime: Within 5-7 working days

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  • Casno:

    104-55-2

    Cinnamaldehyde

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    LIDE PHARMACEUTICALS LIMITED is a professional chemicals and APIs leading manufacturer in China. Our core business line covers APIs, Intermediates, Herb extract, etc.

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  • Cinnamaldehyde Manufacturer 104-55-2 Sparfloxacin Intermediates

  • Casno:

    104-55-2

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  • TIANFU-CHEM CAS:104-55-2 Cinnamaldehyde

  • Casno:

    104-55-2

    TIANFU-CHEM CAS:104-55-2 Cinnamaldehyde

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    104-55-2

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    104-55-2

    MSDS/COA Download

    BLOOM TECH Advanced API/Technology support Cinnamaldehyde CAS 104-55-2

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    104-55-2

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    104-55-2

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    104-55-2

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    104-55-2

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    104-55-2

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    104-55-2

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  • Casno:

    104-55-2

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  • Casno:

    104-55-2

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    Min.Order: 10 Gram

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  • Casno:

    104-55-2

    Cinnamaldehyde

    Min.Order: 1 Metric Ton

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  • factory derictly supply Cinnamaldehyde  with best price

  • Casno:

    104-55-2

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    Product Name: Cinnamaldehyde Synonyms: 3-phenyl-2-propena;3-Phenyl-2-propenaldehyde; CAS: 104-55-2 MF: C9H8O MW: 132.16 EINECS: 203-213-9 Mol File: 104-55-2.mol Melting point −9-−4 °C(lit.) Boiling point 250-252 &d

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  • Casno:

    104-55-2

    MSDS/COA Download

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  • Casno:

    104-55-2

    Cinnamaldehyde

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  • Casno:

    104-55-2

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    Product Name: Cinnamaldehyde Synonyms: 3-PHENYLPROPENAL;AKOS B004060;AKOS BBS-00003207;CINNAMIC ALDEHYDE;CINNAMALDEHYDE;CINNAMALDEHYDE, TRANS-;LABOTEST-BB LT00939010;FEMA 2286 CAS: 104-55-2 MF: C9H8O MW: 132.16 EINECS: 203-213-9 Product Categ

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    Cinnamaldehyde

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History

 Cinnamaldehyde (CAS NO.104-55-2) was isolated from cinnamon essential oil in 1834 by Dumas and Péligot and synthesized in the laboratory by Chiozza in 1856.

Specification

1. Introduction of Cinnamaldehyde
Cinnamaldehyde is the organic compound that gives cinnamon its flavor and odor. This pale yellow, viscous liquid occurs naturally in the bark of cinnamon trees and other species of the genus Cinnamomum. The IUPAC Name of it is (E)-3-phenylprop-2-enal. 

2. Properties of Cinnamaldehyde
Index of Refraction: 1.577
Molar Refractivity: 42.32 cm3
Molar Volume: 127.7 cm3
Polarizability: 16.78×10-24cm3
Surface Tension: 38.9 dyne/cm
Density: 1.034 g/cm3
Flash Point: 71.1 °C
Enthalpy of Vaporization: 48.4 kJ/mol 
Melting Point: −9-−4 °C(lit.)
Boiling Point: 246.8 °C at 760 mmHg
Vapour Pressure: 0.0265 mmHg at 25°C 
Water Solubility: Slightly soluble 
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, strong bases. 
Physical Appearance: yellow liquid with an odour of cinnamon
Product Categories: Pharmaceutical Intermediates;Aromatic Aldehydes & Derivatives (substituted);Alphabetical Listings;C-DFlavors and Fragrances;Certified Natural Products;Flavors and Fragrances

3. Structure Descriptors of Cinnamaldehyde
The molecule of cinnamaldehyde consists of a phenyl group attached to an unsaturated aldehyde. As such, the molecule can be viewed as a derivative of acrolein. Its color is due to the π → π* transition: increased conjugation in comparison with acrolein shifts this band towards the visible.

4. Toxicity of Cinnamaldehyde

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 1160mg/kg (1160mg/kg) BEHAVIORAL: COMA Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.
mouse LD50 intraperitoneal 200mg/kg (200mg/kg)   FAO Nutrition Meetings Report Series. Vol. 44A, Pg. 16, 1967.
mouse LD50 intravenous 75mg/kg (75mg/kg)   U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#07571,
mouse LD50 oral 2225mg/kg (2225mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
Yakugaku Zasshi. Journal of Pharmacy. Vol. 92, Pg. 135, 1972.
mouse LDLo parenteral 200mg/kg (200mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 7, Pg. 687, 1955.
rat LD50 oral 2220mg/kg (2220mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.

5. Safety Information of Cinnamaldehyde

Hazard Codes: IrritantXi
Risk Statements: 36/37/38-43 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R43:May cause sensitization by skin contact.
Safety Statements: 26-36/37 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37:Wear suitable protective clothing and gloves.
WGK Germany: 3
RTECS: GD6476000
F: 10-23
HS Code: 29122900

6. Preparation of Cinnamaldehyde
Although Cinnamaldehyde is obtained from Chinese cassia oils, it is synthesized by action of alkali upon a mixture of benzaldehyde and acetaldehyde.
      C6H5CH=O + CH3CH=O → C6H5CH=CHCH=O
This and most other products for fragrances must be purified by, for example, vacuum fractionation.

7. Use of Cinnamaldehyde
1) The extensive use for Cinnamaldehyde is as a flavoring.Concentrations required for flavoring food items like chewing gum,  candy, ice cream,and beverages range from 9 to 4900 ppm (that is, less than 0.5%).
2) Cinnamaldehyde is used in some perfumes of natural, sweet, or fruity scents. Almond, apricot, butterscotch, and other aromas may partially employ the compound for their pleasant smells.
3) Cinnamaldehyde can be used as a food adulterant; powdered beechnut husk aromatized with cinnamaldehyde can be marketed as powdered cinnamon.
4) Cinnamaldehyde is also used as a fungicide. .

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