DIASTEREO-DIFFERENTIATING SIMMONS-SMITH REACTION USING A NEW CHIRAL AUXILIARY

DOI: 10.1016/S0040-4039(01)80662-6

Source and publish data:

Tetrahedron Letters p. 3807 - 3810 (1989)

Update date:2022-08-03

Topics:

Authors:

Sugimura, Takashi

Futagawa, Tohru

Yoshikawa, Masato

Tai, Akira

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Article abstract of DOI:10.1016/S0040-4039(01)80662-6

Diastereo-differentiating Simmons-Smith reactions of enol ethers of various ketones were carried out by using (3S,5S)-2,6-dimethyl-3,5-heptanediol as a new chiral auxiliary.The diastereomer excess of these reactions reached to be >99 percent.

Full text of DOI:10.1016/S0040-4039(01)80662-6

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