Tetrahedron p. 14623 - 14634 (1999)
Update date:2022-08-03
Topics:
Ngo, Koon-Sin
Brown, Geoffrey D.
The tri-substituted (2,3)-double bond in allohimachalol (1) undergoes autoxidation in the presence of singlet molecular oxygen, resulting in tertiary and secondary allylic hydroperoxides 6 and 7. These autoxidation products may then participate in complex rearrangement reactions to yield seco-allohimachalanes, which have undergone carbon-carbon bond cleavage at the 2,3- or 3,4-positions. The observed autoxidation/rearrangement reactions of 1 in vitro would account for the biogenesis of several allohimachalanes recently reported from the medicinal plant Illicium tsangii as natural products.
View MoreJiaxing Trustworthy Import And Export Co.,Ltd
Contact:+86-573-82030555
Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Shanghai Forever Biotech Co., Ltd.
Contact:+86-21-69734790
Address:Room 5017/5019、5022、5024 of Technology Innovation Centre, No.1155, Gongyuan East Rd, QingPu District, Shanghai China.
Contact:+86-0592 5353131
Address:No.56 Guani Road Software Park 2,Siming District
Nanjing Norris Pharm Technology Co., Ltd.
Contact:+86-13901585132
Address:2 Qiande Road, Jiangning sciencepark Hi-Tech Zone, Nanjing, P.R.China
website:http://www.greenutra.cn
Contact:0086-411-39553357
Address:No. 7-1-1802, Huizhi Garden,Ocean Square,Dalian, 116033, China
Doi:10.1021/ja00706a069
(1970)Doi:10.1016/j.bmc.2009.07.068
(2009)Doi:10.1021/ja01306a050
(1935)Doi:10.1016/S0022-328X(99)00233-8
(2000)Doi:10.1021/acs.orglett.7b00090
(2017)Doi:10.1039/b102578n
(2001)