Anionic living polymerization of monomers with photo-electronic properties for control of polymeric nano architectures

Article abstract of DOI:10.1080/10587250008024853

Block copolymers, 9-ethylcarbazolyl methacrylate (CzMA) with 3-nitro-9-ethylcarbazolyl methacrylate (NCzMA), and styrene with optically functionalized isocyanates containing disperse red 1 (DR1NCO) and (s)-(-)-2-methylbutanol (MBI), were prepared by anionic polymerization for photo-electronic materials. The living condition of CzMA was found at -78°C for 3 h with diethyl zinc and block copolymers of CzMA with NCzMA were synthesized successfully. The polymers show potential to be used as energy transfer materials in UV and PL spectra. Block copolymers of styrene with optically functionalized isocyanates were also synthesized with high yield and the polymers showed the large optical activity at 476 nm.

Full text of DOI:10.1080/10587250008024853

Molecular Crystals and Liquid Crystals Science and
Technology. Section A. Molecular Crystals and Liquid
Crystals
ISSN: 1058-725X (Print) (Online) Journal homepage: http://www.tandfonline.com/loi/gmcl19
Anionic Living Polymerization of Monomers
with Photo-Electronic Properties for Control of
Polymeric Nano Architectures
Yeong-Deuk Shin , Young-Sun Cho , Jang-Joo Kim , Jae-Suk Lee , Song-Hee
Han & Jeong Weon Wu
To cite this article: Yeong-Deuk Shin , Young-Sun Cho , Jang-Joo Kim , Jae-Suk Lee , Song-
Hee Han & Jeong Weon Wu (2000) Anionic Living Polymerization of Monomers with Photo-
Electronic Properties for Control of Polymeric Nano Architectures, Molecular Crystals and
Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals,
349:1, 9-14, DOI: 10.1080/10587250008024853
To link to this article: http://dx.doi.org/10.1080/10587250008024853
Published online: 24 Sep 2006.
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Date: 05 June 2016, At: 04:38