Tetrahedron Letters p. 8255 - 8259 (1999)
Update date:2022-08-04
Topics:
Bailey, Patrick D.
Morgan, Keith M.
Rosair, Georgina M.
Thomas, Rhodri Ll.
The one-pot conversion of ajmaline 1 into the nitrile 4 (X-ray structure) and suaveoline 2a is reported; both reactions utilise hydroxylamine hydrochloride in a refluxing alcohol, and involve unusual multi-step mechanisms in which the product ratio can be
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