Stereocontrolled synthesis of optically active β-D-glucopyranosides of 3-hydroxy-7,8-didehydro-β-ionol

DOI: 10.1248/cpb.48.2017

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Chemical and Pharmaceutical Bulletin p. 2017 - 2018 (2000)

Update date:2022-08-05

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Authors:

Yamano, Yumiko

Watanabe, Yasuko

Watanabe, Naoharu

Ito, Masayoshi

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Article abstract of DOI:10.1248/cpb.48.2017

A stereocontrolled synthesis of optically active β-D-glucopyranosides 1-4 of 3-hydroxy-7,8-didehydro-β-ionol utilizing an asymmetric transfer hydrogenation to α,β-acetylenic ketones catalyzed by chiral ruthenium complexes as the key step is described.

Full text of DOI:10.1248/cpb.48.2017

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