Bulletin of the Chemical Society of Japan p. 3035 - 3036 (1980)
Update date:2022-08-02
Topics:
Kajihara, Yasushi
Ishikawa, Katsuhiro
Yasuda, Hajime
Nakamura, Akira
A series of isoprene coupling dimers bonded at 1-2, 1-3, 1-4, 2-4, 3-4, or 4-4 position was prepared by regiocontrolled catalysis of transition metals or without catalysts in the reaction of 2-methyl-2-butene-1,4-diylmagnesium or 3-methyl-2-butenylmagnesium chloride with C5-alkenyl halides.
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