CH bond activation in cations of the type {[(2,4,6-Me3 C6H2NCH2CH2)2NMe] ZrR}+ and a simple solution that yields a catalyst for the living polymerization of 1-hexene

DOI: 10.1021/om000972f

Source and publish data:

Organometallics p. 1056 - 1058 (2001)

Update date:2022-07-30

Topics:

Authors:

Schrock, Richard R.

Bonitatebus Jr., Peter J.

Schrodi, Yann

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Article abstract of DOI:10.1021/om000972f

{[(MesNCH₂CH₂)₂NMe]ZrMe} [B(C₆F₅)₄] and intermediates in the polymerization reaction of 1-hexene that are formed from it decompose as a consequence of CH activation in an ortho methyl group

Full text of DOI:10.1021/om000972f

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Product name:[Zr(CH₃)2((2,6-Cl₂C₆H₃NCH₂CH₂)2NMe)]

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