105337-03-9Relevant articles and documents
Rhodium-Catalyzed cross-coupling of arylboronic acids using vinyl acetate as the electrophilic partner
Lee, Hang Wai,Kwong, Fuk Yee
, p. 3151 - 3154 (2009)
The first Suzuki-type cross-coupling between arylboronic acids and vinyl acetate is disclosed. The acetoxy moiety as the leaving group is realized in the coupling process. Rhodium complexes were found to be highly effective for promoting this transformati
Block copolystyrene derivatives having flexible alkylsulfonated side chains and hydrophobic alkoxy chains as a proton exchange membrane for fuel cell application
Sheng, Li,Higashihara, Tomoya,Maeda, Rina,Hayakawa, Teruaki,Ueda, Mitsuru
, p. 2216 - 2224 (2013)
A series of block copolystyrene derivatives, poly{[4-(4-sulfobutyloxy) styrene]x-block-[4-(n-butoxystyrene)]y} (PSBOS x-b-PnBOSy), containing a flexible alkylsufonated side chain and hydrophobic alkoxy chain with various ion exchange capacities (IECs) have been synthesized based on living anionic polymerization. The resulting crosslinked membranes were prepared using 4,4′-methylene-bis[2,6- bis(hydroxyethyl)phenol] as the crosslinker in the presence of methanesulfonic acid. The crosslinked PSBOS2.2-b-PnBOS1 membrane with IEC of 2.89 mequiv g-1 displays a high proton conductivity (0.01 S cm-1) at 30% relative humidity and 80 °C, which is comparable to that of Nafion. The well-developed phase separation and the continuous hydrophilic domains in the crosslinked PSBOS2.2-b-PnBOS1 membranes have been observed in a transmission electron microscope image. Moreover, the dynamic mechanical analysis measurement and Fenton's reagent testing show that the crosslinked PSBOSx-b-PnBOSy membranes have good mechanical properties and oxidative stability. These results indicate that the introduction of flexible alkylsulfonated side chains to the polystyrene main chains positively affect both the proton conductivity and oxidative stability.
Supramolecular gels derived from nucleoside based bolaamphiphiles as a light-sensitive soft material
Baillet, Julie,Gaubert, Alexandra,Bassani, Dario M.,Verget, Julien,Latxague, Laurent,Barthélémy, Philippe
supporting information, p. 3397 - 3400 (2020/03/30)
Light-sensitive Low Molecular Weight Gelators (LMWGs) derived from glyconucleoside bolaamphiphiles containing a stilbene unit displayed gelation abilities in hydroalcoholic mixtures. These materials showed a gel-sol transition under UV irradiation thanks to E-Z isomerization of stilbene and could find potential applications as drug delivery systems.
Synthesis of New Liquid Crystalline Compounds based on 1,4-Diarylbuta-1,3-dienes
Brettle, Roger,Dunmur, David A.,Hindley, Nigel J.,Marson, Charles M.
, p. 775 - 782 (2007/10/02)
A group of (E,E)-1,4-diarylbuta-1,3-dienes, substituted in the para-position of one aryl ring by an alkoxy-group and in the para-position of the other aryl group by a cyano- or halogeno-group have been synthesised.The compounds are mesogenic and their phy