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Photochemical & Photobiological Sciences
Page 12 of 13
DOI: 10.1039/C5PP00197H
ARTICLE
Journal Name
24 S. Khatua, J. M. Guerrero, K. Claytor, G. Vives, A. B. 43 K. Sonogashira, Development of Pd–Cu catalyzed cross-
coupling of terminal acetylenes with sp2-carbon halides, J.
Organomet. Chem., 2002, 653, 46-49.
Kolomeisky, J. M. Tour, S. Link, Micrometer-scale translation
and monitoring of individual nanocars on glass, ASC Nano,
2009,
3
, 351-356.
44 K. Sonogashira, Y. Tohda, N. Hagihara, Convinient synthesis
of acetylenes – catalytic substitutions of acetylenic hydrogen
with bromoalkanes, iodoarenes and bromopyridines,
Tetrahedron Lett., 1975, 16, 4467-4470.
25 G. Vives, J. M. Tour, Synthesis of single-molecule nanocars,
Acc. Chem. Res., 2009, 42, 473-487.
26 S. Sankararaman, G. Venkataramana, B. Vrghese,
Conformational isomers from ratation of diacetylenic bond 45 C. A. Glaser, BeiträgezurKenntniss des Acetenylbenzols, Ber.
in an ethynylpyrene molecular hinge, J. Org. Chem., 2008, 73 Dtsch. Chem. Ges., 1869, , 422-424.
,
2
2404-2407.
46 P. W. Thulstrup, S. V. Hoffmann, B. K. V. Hansen, J. Spanget-
Larsen, Unique interplay between electronic states and
dihedral angle for the molecular rotor diphenyldiacetylene,
Phys. Chem. Chem. Phys., 2011, 13, 16168-16174.
27 A. Sakar, S. S. Talwar, Heteroaryl functionalised diacetylene:
preparation and solid-state reactivity, J. Chem. Soc., Perkin
Trans. 1, 1998, 4141-4146.
28 D. Y. Ahn, J. M. Kim, Fluorogenic polydiacetylene 47 A. Beeby, K. Findlay, P. J. Low, T. B. Marder, A re-evaluation
supramolecules: immobilization, micropattering and
application to label-free chemosensors, Acc. Chem. Res.,
2008, 47, 805-816.
of
the
photophysical
bis(phenylethynyl)benzene:
properties
a
of
model
1,4-
for
poly(phenyleneethynylene), J. Am. Chem. Soc., 2002, 124
8280-8284.
,
29 K. Okuyama, T. Hasegawa, M. Ito, N. Mikami, Electronic
spectra of tolan in supersonic free jet; large-amplitude 48 P. V. James, P. K. Sudeep, C. H. Suresh, K. G. Thomas,
torsional motion, J. Phys. Chem., 1984, 88, 1711-1716.
30 Y. Hirata, T. Okada, N. Mataga, Picosecond time-resolved
absorption spectrum measurements of the higher excited
singlet state of diphenylacetylene in the solution phase, J.
Phys. Chem., 1992, 96, 6559-6563.
31 C. Ferrante, U. Kensy, B. Dick, Does diphenylacetylene (tolan)
fluoresce from its second excited singlet state?
Semiempirical MO calculations and fluorescence quantum
yield measurements. J. Phys. Chem., 1993, 97, 13457-13463.
32 Y. Hirata, T. Okada, T. Nomoto, Photophysical properties of
diphenylacetylene derivatives in the solution phase;
Photophysical and theoretical investigation of oligo(p-
phenyleneethynylene)s: effect of aloxy substitution and
alkyne-aryl bond rotations, J. Phys. Chem. A, 2006, 110
4329-4337.
,
49 A. Beeby, K. S. Findlay, A. E. Goeta, L. Porres, S. R. Rutter, A.
L. Thomson, Engineering twist in 9,10-
diethynylanthracenes by steric interactions, Photochem.
Photobiol. Sci., 2007, , 982-986.
a
6
50 G. Duvanel, J. Grilj, A. Schuvey, A. Gossauer, E. Vauthey,
Ultrafast excited-state dynamics of phenyleneethylene
oligomers in solution, Photochem. Photobiol. Sci., 2007, 6,
comparison
diphenylbutadiyne, Chem. Phys. Lett., 1998, 293, 371-377.
33 Y. Hirata, T. Okada, T. Nomoto, Photophysical properties of
diphenylacetylene and diphenylbutadiyne derivatives in
solution phase, Acta Phys. Polonica A, 1998, 94, 627-636.
34 Y. Hirata, Photophysical and photochemical primary
with
the
dynamical
properties
of
952-963.
51 L. Gutierez-Arzaluz, C. A. Guarin, W. Rodrigez-Cordoba, J.
Peon, Dynamics of the formation of a charge transfer state in
1,2-bis(9-anthryl)acetylene in polar solvents: symmetry
reduction with the participation of an intramolecular torsion
coordinate, J. Phys. Chem. B, 2013, 117, 12175-12183.
processes of diphenylacetylene derivatives and related 52 M. I. Sluch, A. Godt, U. H. F. Bunz, M. A. Berg, Excited-state
compounds in liquid phase, Bull. Chem. Soc. Jpn., 1999, 72,
dynamics of oligo(p-phenyleneethynylene): quadratic
coupling and torsion motions, J. Am. Chem. Soc., 2001, 123,
6447-6448.
switching of the fluorescence excited state in α,ω- 53 L.T. Liu, D. Yaron, M.I. Sluch, M.A. Berg, Modeling the effects
1647-1664.
35 Y. Nagano, T. Ikoma, K. Akiyama, S. Tero-Kubota, Symmetry
diphenylpolyynes, J. Am. Chem. Soc., 2003, 125, 14103-
14112.
36 M. Wierzbicka, I. Bylińska, C. Czaplewski, W. Wiczk,
of torsional disorder on the spectra of poly- and oligo-(p-
phenyleneethynylenes), J. Phys. Chem. B, 2006, 110, 18844-
18852.
Experimental and theoretical studies of spectroscopic 54 L. T. Liu, D. Yaron, M. A. Berg, Electron−phonon coupling in
properties of simple symmetrically substituted phenyleneethynylene oligomers:ꢁ nonlinear one-
, 29294-
a
diphenylacetylene derivatives, RSC Adv., 2015,
29303.
5
dimensional configuration-coordinate model, J. Phys. Chem.
C, 2007, 111, 5770-5782.
37 M. Wierzbicka, I. Bylińska, A. Sikorski, C. Czaplewski, W. 55 K. Schmieder, M. Levitus, H. Dang, M. A. Gracia-Garibay,
Wiczk, Experimental and theoretical studies of spectroscopic
properties of simple symmetrically substituted diphenylbuta-
1,3-diyne derivatives, Photochem. Photobiol. Sci., submitted.
38 M. Z. Zgierski, E. C. Lim, Nature of the „dark” state in
Photophysical properties of coplanar and twisted 1,4-Bis(9-
ethynylanthracenyl)benzene. Rotational equilibration in the
excited states of diaryalkynes, J. Phys. Chem. A, 2002, 106
1551-1556.
,
diphenylacetylene and related molecules: state switch from 56 T. Fujiwara, M. Z. Zgierski, E. C. Lim, Spectroscopy and
photophysics of 1,4-bis(phenylethynyl)benzene: effects of
linear ππ* state to the bent πσ* state, Chem. Phys. Lett.,
2004, 387, 353-355.
39 M. Z. Zgierski, T. Fujiwara, E. C. Lim, Role of the πσ* state in
molecular photophysics, Acc. Chem. Res., 2010, 43, 806-817.
40 J. Saltiel, V. K. R. Kumar, Photophysics of diphenylacetylene:
ring torsion and dark σπ* state, J. Phys. Chem. A, 2008, 112
4736-4741.
57 Y. Hirata, T. Okada, T. Nomoto, Photophysical properties of
diphenylacetylene derivatives in solution phase III. Thermal
,
light from the “dark state” J. Phys. Chem. A, 2012, 116
,
repopulation
of
the
S2
state
of
(aminophenyl)phenylacetylene, J. Phys. Chem., 1993, 97,
10548-10558.
41 R. Gleiter, D. B. Werz, Alkynes between main group
9677-9681
elements: from dumbbells via rods to squares and tubes, 58 Y. Hirata, T. Okada, T. Nomoto, Higher excited singlet state of
Chem. Rev., 2010, 110, 4447-4488.
42 U. H. F. Bunz, K. Seehafer, M. Bendera, M. Porza,
diphenylacetylene in solution phase. Chem. Phys. Lett., 1993,
209, 397–402.
Poly(aryleneethynylene)s (PAE) as paradigmatic sensor 59 Y. Hirata, T. Okada, T. Nomoto, Photophysical properties of
cores, Chem. Soc. Rev., DOI: 10.1039/c4cs00267a
diphenylacetylene derivatives in solution phase. IV. N,N-
12 | J. Name., 2012, 00, 1-3
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