Journal of Organic Chemistry p. 6386 - 6387 (1992)
Update date:2022-08-03
Topics:
Yanagisawa, Akira
Hibino, Hiroaki
Habaue, Shigeki
Hisada, Yoshiyuki
Yamamoto, Hisashi
The highly α,α' selective and stereocontrolled homocoupling reaction of allylic halides was achieved using barium reagent.The double-bond geometry of the starting allylic chloride was completely retained. α,α' Cross-coupling products were also prepared stereospecifically and regioselectively by this method.
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