Journal of the Chemical Society. Perkin transactions II p. 1537 - 1540 (1988)
Update date:2022-08-03
Topics:
Lee, Ikchoon
Choi, Yong Hoon
Lee, Hai Whang
Lee, Byung Choon
Kinetics of reactions between 2-phenylethyl benzenesulphonates and anilines in methanol at 65.0 deg C have been studied; the mechanism is discussed on the basis of cross interaction constants, ρij.The overall reaction was found to proceed by a dissociative SN2 mechanism with a relatively small degree of aryl participation.The fraction of the phenonium ion intermediate captured by the nucleophile, aniline, in the aryl-assisted pathway has been shown to increase with a stronger nucleophile, and a four-centre transition state in an intermolecular SNi mechanism is suggested for the aryl-unassisted pathway.
View MoreShanghai Taibao Pharmaceutical Technology Co., Ltd(expird)
Contact:021-52217366
Address:shanghai
GUANGZHOU MEDCAN PHARMATECH LTD
website:http://www.gzmedcan.com
Contact:+86-20-82519649
Address:Building J,Room 101,1 JiangtashanRd,Guang Zhou Science City,Guang Zhou ,China
website:http://www.chinacharm.cn/
Contact:86 551 5316260
Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
Liaoning Yufeng Chemical Co.,Ltd.
Contact:86-0419-3418888
Address:The metallurgical industrial zone,shoushan town, Liaoyang, Liaoning, China
Hebei DaPeng Pharm & Chem Co., Ltd.
Contact:86-317-7298678,0576-88861898 88861908
Address:West Songmen Village, East Songmen Town, Wuqiao, Cangzhou, Hebei ,China
Doi:10.1002/1521-3765(20010803)7:15<3342::AID-CHEM3342>3.0.CO;2-7
(2001)Doi:10.1039/jr9650004464
(1965)Doi:10.1016/j.bmcl.2014.10.008
(2014)Doi:10.1002/anie.201804917
(2018)Doi:10.1016/S0040-4020(01)00698-6
(2001)Doi:10.1021/jo01345a064
(1966)
