28987-70-4Relevant academic research and scientific papers
Kinetics and Mechanism of the Reactions between Chloranil and n-Butylamine in Cyclohexane Solution
Monzo, Isidro S.,Palou, Juan,Roca, Jose,Valero, Rosa
, p. 1995 - 1998 (1988)
Interaction between chloranil (CA) and n-butylamine (A) at several temperatures has been studied by u.v.-visible spectroscopy.Kinetic and thermodynamic parameters, as well as a mechanism, have been proposed for this reaction.The results indicate the initial formation of charge-transfer complexes between CA and A, in the presence of an excess of amine, which decomposes to give a final product (D) (disubstituted product of CA).The reaction path is autocatalysed by the presence of amine.
NEW SYNTHESIS OF TRIPHENODITHIAZINES AND TRIPHENODITHIAZINEQUINOES.
Nishi,Hatada,Kitahara
, p. 1482 - 1486 (2007/10/02)
A new class of 6,13-bis(arylamino)triphenodithiazines has been synthesized by condensing chloranil with arylamines followed by the reaction of the resulting 2,5-bis(arylamino)-3,6-dichloro-1,4-benzoquinones with zinc 2-aminobenzenthiolates in the presence
