
Phosphorus, Sulfur and Silicon and the Related Elements p. 129 - 142 (2001)
Update date:2022-09-26
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Cycloaddition of 2-[(N-phenyl)thiocarboxamido-]-4-methyl-2H-1,4-benzoxazin-3-one (2) to α,β-unsaturated compounds gave spiro pyridine derivatives. Reaction of compound 2 with some halo compounds afforded thiazolidine derivatives. 2-Ethoxymethylenyl-4-methyl-1,4-benzoxazine-3-thione underwent cyclocondensation reactions with some bidentate reagents. Condensed tricyclic systems have been prepared through the reaction of 3-dicyanomethylenyl-4-methyl-2H-1,4-benzoxazine with the appropriate reagents.
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