CONVERSION OF THE CHOLESTEROL SIDECHAIN TO A 17-ACETYL GROUP BY REMOTE CHLORINATION REACTIONS

DOI: 10.1016/S0040-4039(00)84722-X

Source and publish data:

Tetrahedron Letters p. 3087 - 3090 (1986)

Update date:2022-08-05

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Authors:

Maitra, Uday

Breslow, Ronald

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Article abstract of DOI:10.1016/S0040-4039(00)84722-X

Two methods to convert cholesterol to pregnane derivatives are described.In one, template directed chlorination of C-20 with an iodoaryl ester attached at the 6 β position was used to convert i-cholesterol to pregnenolone.

Full text of DOI:10.1016/S0040-4039(00)84722-X

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