Australian Journal of Chemistry p. 455 - 459 (1980)
Update date:2022-08-04
Topics:
Alberts, Vincent
Carman, Raymond M.
Iodobromination of propene gives a mixture (c. 60:40) of 2-bromo-1-iodopropane and 1-bromo-2-iodopropane.This mixture of kinetic control converts into an equilibrium (c. 70:30) mixture with heat.The addition to the double bond is postulated to occur through a bridged iodonium ion rather than through a simple carbocation, and hence Markownikoff's rule need not apply to this system
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