Acta Crystallographica, Section C: Crystal Structure Communications p. m68-m69 (2002)
Update date:2022-07-30
Topics:
Hayton, Trevor W.
Legzdins, Peter
Rettig, Steven J.
A report on the synthesis of [Mo(C5H5)(C6H4FO)(C4 H11Si)(NO)] by reacting CpMo(NO)(CH2SiMe3)2 where Cp denoted cyclopentadienyl, with one equivalent of p-FC6H4OH was presented. The piano-stool molecular structure was exhibited by the complex. A pseudo-tetrahedral geometry around the Mo atom was observed by the compound. The nitrosyl ligand was found to be involved in π-back-bonding with the Mo centre.
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