Vinyl hydrogen more reactive than benzyl hydrogen toward base in significantly twisted styrenes

DOI: 10.1016/S0040-4039(01)00308-2

Source and publish data:

Tetrahedron Letters p. 3093 - 3095 (2001)

Update date:2022-08-03

Topics:

Authors:

Mori, Hajime

Matsuo, Takafumi

Yoshioka, Yasunori

Katsumura, Shigeo

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Article abstract of DOI:10.1016/S0040-4039(01)00308-2

The novel example of vinyl hydrogen more reactive than benzylic hydrogen was found by treatment of a twisted styrene derivative with a strong base followed by D₂O quenching. The characteristic nature of the vinyl hydrogen, which is activated by

Full text of DOI:10.1016/S0040-4039(01)00308-2

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