10.1002/anie.201805483
Angewandte Chemie International Edition
COMMUNICATION
Reaction conditions: Alkene (1 mmol), HBPin (3 mmol), [Mn] (2 mol%),
NaOtBu (6 mol%), neat, 60 °C, 18 h. Isolated yields. Regioselectivities are
reported below the yield in parentheses as a ratio of linear:branched isomers.
S.P.T. acknowledges the Royal Society for a University Research
Fellowship. J.R.C. and S.P.T. acknowledge AstraZeneca for a
PhD studentship.
Keywords: manganese • catalysis • hydrosilylation • alkenes •
hydroboration
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