Tetrahedron Letters p. 349 - 352 (1990)
Update date:2022-09-26
Topics:
Gaudemar, Marcel
Bellassoued, Moncef
Treatment of acetaldehyde N-ter-butylimine by two equivalents of LDA, followed by trimethylsilyl chloride trapping affords the α,α-disilylated imine; the latter reacts with aromatic aldehydes producing α,β-ethylenic aldehydes in excellent yields and with very high stereoselectivity in favour of the E isomer.
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