Journal of Organic Chemistry p. 1695 - 1699 (1987)
Update date:2022-08-04
Topics:
Mitsudo, Take-aki
Kadokura, Mamoru
Watanabe, Yoshihisa
Diphenylketene and ethylphenylketene react with allylic carbonates or acetates in the presence of a catalytic amount of tetrakis(triphenylphosphine)palladium to give α-allylated esters or 1,3-dienes, respectively.For example, the reaction of diphenylketene with allyl methyl carbonate in DMF at 0 deg C gave methyl 2,2-diphenyl-4-pentenoate in 67percent yield.The reaction of diphenylketene with allyl acetate in benzene at 25 deg C gave 1,1-diphenyl-1,3-butadiene in 72percent yield.Marked solvent effects were observed.
View MoreContact:+86-533-3112891
Address:zibo
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD
Contact:86-561-4080321
Address:No.8 Lieshan Industrial Zone of Huaibei
Qingdao Kingway Pharmtech Co., Ltd.
Contact:86-532-87118899
Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Geen Chemical Technology Co., Ltd
Contact:86-769-21660847
Address:1408, Yingfeng Commercial Center, Nancheng District
website:http://www.josunpharma.com
Contact:+86-311-80715268 80766839
Address:No.39, Zhaiying Street, Shijaizhuang,Hebei,China
Doi:10.1016/j.molstruc.2006.12.043
(2007)Doi:10.1021/ja00361a014
(1983)Doi:10.1002/jhet.5570190317
(1982)Doi:10.1039/P29820001055
(1982)Doi:10.1016/j.tetlet.2014.04.017
(2014)Doi:10.1016/0968-0896(96)00131-9
(1996)
