MEVINIC ACIDS AND ANALOGS : A NOVEL EFFICIENT ROUTE TO CHIRAL SYNTHONS FROM 1,6-ANHYDRO-D-GLUCOSE

DOI: 10.1016/S0040-4039(01)93842-0

Source and publish data:

Tetrahedron Letters p. 6015 - 6018 (1989)

Update date:2022-07-30

Topics:

Authors:

David, C.

Gesson, J.P.

Jacquesy, J.C.

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Article abstract of DOI:10.1016/S0040-4039(01)93842-0

1,6-anhydro-D-glucose is efficiently and regioselectively deoxygenated at C-2 and C-4 by displacement of the corresponding ditosylate with thiophenol followed by Raney Ni hydrogenolysis.This route provides a short access to chirons of the key lactonic moi

Full text of DOI:10.1016/S0040-4039(01)93842-0

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