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Heterogeneous fluorination of allylic halides by the combination of lead fluoride and a sodium salt

DOI: 10.1016/0022-1139(94)03161-R

Source and publish data:

Journal of Fluorine Chemistry p. 131 - 134 (1995)

Update date:2022-08-04

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Authors:

Ichihara, JunkoIchihara, Junko

Takai, YoshioTakai, Yoshio

Hanafusa, TerukiyoHanafusa, Terukiyo

Tomioka, KiyoshiTomioka, Kiyoshi

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Article abstract of DOI:10.1016/0022-1139(94)03161-R

The composite solid reagent consisting of lead(II) fluoride and a small amount of sodium bromide has been found to facilitate the fluorination of allylic halides in acetonitrile to afford a mixture of the corresponding and rearranged fluorides in the ratio of 1:1 to 1:2.Such allylic rearrangement is not observed when KF/18-crown-6 or tetrabutylammonium fluoride are employed. - Keywords: Heterogeneous fluorination; Allylic halides; Lead fluoride; Sodium salts; NMR spectroscopy

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Full text of DOI:10.1016/0022-1139(94)03161-R

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