Journal of Fluorine Chemistry p. 131 - 134 (1995)
Update date:2022-08-04
Topics:
Ichihara, Junko
Takai, Yoshio
Hanafusa, Terukiyo
Tomioka, Kiyoshi
The composite solid reagent consisting of lead(II) fluoride and a small amount of sodium bromide has been found to facilitate the fluorination of allylic halides in acetonitrile to afford a mixture of the corresponding and rearranged fluorides in the ratio of 1:1 to 1:2.Such allylic rearrangement is not observed when KF/18-crown-6 or tetrabutylammonium fluoride are employed. - Keywords: Heterogeneous fluorination; Allylic halides; Lead fluoride; Sodium salts; NMR spectroscopy
View MoreZibo Kunran Enterprises Co. LTD
website:http://www.kunranchem.com
Contact:0086 533 5200669
Address:No. 96 Jinjing Avenue, Zibo, Shandong, China
Shanghai Bocimed Pharmaceutical Co., Ltd.
website:http://www.bocimed.com
Contact:+86-21-68861632
Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Wuhan Yitongtai Science and Technology Co.,Ltd.
Contact:+86-27-88933550
Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
KangZhiYuan Pharmaceutical Company Limited
Contact:(Sabrina)86-20-85273232
Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Contact:+86-511-88790000
Address:338 North Yushan Rd, Zhenjiang, Jiangsu 212016
Doi:10.1139/v74-461
(1974)Doi:10.1248/cpb.22.757
(1974)Doi:10.1021/ol030023t
(2003)Doi:10.1002/hlca.19780610138
(1978)Doi:10.1023/A:1023345313956
(2002)Doi:10.1016/S0022-328X(97)00428-2
(1998)
